 | Chris Evans als Steve Rogers / Captain America |
 | Robert Downey Jr. als Tony Stark / Iron Man |
 | Scarlett Johansson als Natasha Romanoff / Black Widow |
 | Sebastian Stan als James 'Bucky' Barnes / Winter Soldier |
 | Chadwick Boseman als T'Challa / Black Panther |
 | Daniel Brühl als Baron Helmut Zemo |
 | Elizabeth Olsen als Wanda Maximoff / Scarlet Witch |
 | Paul Bettany als Vision |
 | Don Cheadle als Lieutenant James 'Rhodey' Rhodes / War Machine |
 | Anthony Mackie als Sam Wilson / Falcon |
 | Tom Holland als Peter Parker / Spider-Man |
 | Jeremy Renner als Clint Barton / Hawkeye |
 | Paul Rudd als Scott Lang / Ant-Man |
 | Emily VanCamp als Sharon Carter / Agent 13 |
 | Martin Freeman als Everett K. Ross |
 | William Hurt als Secretary of State Thaddeus 'Thunderbolt' Ross |
 | John Kani als King T'Chaka |
 | Marisa Tomei als May Parker |
 | Frank Grillo als Brock Rumlow / Crossbones |
 | John Slattery als Howard Stark |
 | Hope Davis als Maria Stark |
 | Alfre Woodard als Miriam Sharpe |
 | Michael A. Cook als MRI Tech |
 | Laughton Parchment als Vicar |
 | Jackson Spidell als Josef / Super Soldier #1 |
 | Yi Long als Super Soldier #2 |
 | Heidi Moneymaker als Super Soldier #3 |
 | Aaron Toney als Super Soldier #4 |
 | Cale Schultz als Super Soldier #5 |
 | Ann Russo als Zemo's Wife (voice) |
 | Gene Farber als Vasily Karpov |
 | Florence Kasumba als Ayo |
 | Cornell John als Attaché |
 | Sven Hönig als Man at Kiosk |
 | Joshua Peck als GSG9 Task Force Gunner |
 | Brent McGee als GSG9 Task Force Pilot |
 | Be Satrazemis als German Innkeeper |
 | Blair Jasin als Raft Guard |
 | Oliver Bigalke als Barge Man #1 |
 | Rafael Banasik als Barge Man #2 |
 | David de Vries als Custodian |
 | Katie Amess als Woman in Lobby #1 |
| Austin Sanders als Woman in Lobby #2 |
 | Brett Gentile als Delivery Truck Driver |
 | John Curran als Funeral Director |
| Matthew Anderson als Choir |
| Andrew Botchwey als Choir |
| Chase Bradfield als Choir |
| Ernest Charles als Choir |
| Hendricks Coates als Choir |
| Ethan Condon als Choir |
| Shen Dynes als Choir |
| Nathaniel Ellis als Choir |
| Jariah Ferguson als Choir |
| Evan Ffrench als Choir |
| Justin Freeman als Choir |
| Ralphael Grand'Pierre als Choir |
| Julian Grimes als Choir |
| Aaron Hayes als Choir |
| Austin Hooper als Choir |
| Amiri Jones als Choir |
| Myles Joseph als Choir |
| Stephen Lewis als Choir |
| Jacob Ludwick als Choir |
| D'Mahrei McRae als Choir |
| Ashwin Mudaliar als Choir |
| Eli Ollinger als Choir |
 | Parker Pape als Choir |
| Daniel Parada als Choir |
| Jonah Ruffin als Choir |
| Darryl Sampson als Choir |
| Cameron Sardone als Choir |
| Stanley Sellers als Choir |
| Miles Selles als Choir |
| Jacob Sung als Choir |
| Caden Wilkinson als Choir |
 | Jin Shijia als Chinese Newscaster |
 | Jessica Walther-Gabory als German Newscaster #1 |
 | Beniamino Brogi als German Newscaster #2 |
 | Silvina Buchbauer als News Reporter |
| Henry Amadi als Busboy (Lagos) |
| Ugochukwu Ani als Waiter (Lagos) |
| Michael Anthony Rogers als Secretary Ross's Aide |
| Damion Poitier als Hero Merc #1 |
 | Umar Khan als Hero Merc #2 |
| David E. Brown als Hero Merc #3 |
| Guy Fernandez als Hero Merc #4 |
 | Jim Rash als M.I.T. Liaison |
| Sophia Russo als Teenage Girl |
 | Stan Lee als FedEx Driver |
 | Amelia Morck als UN Staffer Gibson |
 | Kerry Condon als F.R.I.D.A.Y. (voice) |
 | Julianna Guill als Stark's Assistant |
 | Surely Alvelo als Nurse |
 | Brian Schaeffer als Cultural Attaché |
| Kevin LaRosa Jr. als Helicopter Pilot |
| Al Cerullo als Helicopter Pilot |
 | Frédéric North als Helicopter Pilot |
 | Joe Russo als Dr. Theo Broussard (uncredited) |
 | Ray Sahetapy als Auctioneer (uncredited) |
 | Chris Jai Alex als IFID (uncredited) |
 | Scott Hunter als Crossbones’ Mercenary (uncredited) |
| Kimberly Hester Huffstetler als MIT Grad |
 | Lucie Carroll als U.N. Diplomat (uncredited) |
| Christopher Markus | Screenplay |
| Stephen McFeely | Screenplay |
| Kevin Feige | Producer |
| Joe Simon | Characters |
| Jack Kirby | Characters |
| Jeffrey Ford | Editor |
| Henry Jackman | Original Music Composer |
| Alan Fine | Executive Producer |
| Lars P. Winther | Associate Producer |
| Mitchell Bell | Co-Producer |
| Trent Opaloch | Director of Photography |
| Louis D'Esposito | Executive Producer |
| Stan Lee | Executive Producer |
| Nate Moore | Executive Producer |
| Henning Molfenter | Co-Producer |
| Christoph Fisser | Co-Producer |
| Charlie Woebcken | Co-Producer |
| Patricia Whitcher | Executive Producer |
| Victoria Alonso | Executive Producer |
| Sarah Halley Finn | Casting |
| Owen Paterson | Production Design |
| Judianna Makovsky | Costume Design |
| Ronald R. Reiss | Set Decoration |
| Gregory S. Hooper | Art Direction |
| Greg Berry | Supervising Art Director |
| Theresa Greene | Art Department Coordinator |
| Andres Cubillan | Assistant Art Director |
| Matthew Gatlin | Assistant Art Director |
| Jim Wallis | Assistant Art Director |
| Michael Fissneider | Assistant Art Director |
| Stacey S. McIntosh | Construction Coordinator |
| Tara Feldstein Bennett | Casting |
| Chase Paris | Casting |
| Jason B. Stamey | Casting Associate |
| Hayden Bilson | Armorer |
| Ron Licari | Armorer |
| Larry Zanoff | Armorer |
| Joel Thingvall | Researcher |
| Daniel Pinder | Music Editor |
| Dave Jordan | Music Supervisor |
| Nick Scarano | Costume Supervisor |
| Pablo Borges | Assistant Costume Designer |
| Michael Crow | Assistant Costume Designer |
| Lisa Tomczeszyn | Assistant Costume Designer |
| Chris Allegro | Set Costumer |
| Valentina Aulisi | Set Costumer |
| David Butler | Set Costumer |
| Steven Butler | Set Costumer |
| Dustin Fletcher | Set Costumer |
| Maurice K. McGuire | Camera Operator |
| Onofrio Nino Pansini | Camera Operator |
| Jörg Widmer | Camera Operator |
| Charles Schner | Camera Operator |
| Michael J. Walker | Camera Operator |
| Eric Laudadio | Camera Operator |
| Jeremy Braben | Helicopter Camera |
| David B. Nowell | Helicopter Camera |
| Mark Goellnicht | Steadicam Operator |
| Zade Rosenthal | Still Photographer |
| Jeff Murrell | Gaffer |
| Albrecht Silberberger | Gaffer |
| Joshua Davis | Gaffer |
| Mike Pearce | Gaffer |
| Peter Hawkins | Additional Camera |
| Camille Friend | Hair Department Head |
| Cydney Cornell | Hairstylist |
| Jeri Baker | Hairstylist |
| Robert Wilson | Hairstylist |
| Fawn Ortega | Makeup Artist |
| Laura Dandridge | Makeup Artist |
| Allan A. Apone | Makeup Artist |
| Deborah La Mia Denaver | Makeup Artist |
| Ryan J. Frias | Dialogue Editor |
| Stuart McCowan | Dialogue Editor |
| Randall L. Johnson | Boom Operator |
| Etienne Haug | Boom Operator |
| Malo Thouément | Boom Operator |
| Shelley Roden | Foley |
| Shannon Mills | Sound Designer |
| Jeremy Bowker | Sound Effects Editor |
| Tom Johnson | Sound Re-Recording Mixer |
| Juan Peralta | Sound Re-Recording Mixer |
| Shannon Mills | Supervising Sound Editor |
| Daniel Laurie | Supervising Sound Editor |
| Pimentel A. Raphael | Animation Supervisor |
| Simone Kraus Townsend | Animation Supervisor |
| David Marsh | CG Supervisor |
| Pavel Pranevsky | CG Supervisor |
| Gerd Nefzer | Special Effects Coordinator |
| Carlo Perez | Special Effects Supervisor |
| Daniel Sudick | Special Effects Supervisor |
| Matthew Lloyd | Visual Effects Coordinator |
| Sean McGrath | Visual Effects Coordinator |
| Jennifer Mizener | Visual Effects Coordinator |
| Brittany Montero | Visual Effects Coordinator |
| Adam Pere | Visual Effects Coordinator |
| Cole Darby | Visual Effects Coordinator |
| Samuel Perkins | Visual Effects Editor |
| Jen Underdahl | Visual Effects Producer |
| Huseyin Caner | Visual Effects Supervisor |
| Dan DeLeeuw | Visual Effects Supervisor |
| Jamie Hallett | Visual Effects Supervisor |
| Russell Earl | Visual Effects Supervisor |
| Vincent Cirelli | Visual Effects Supervisor |
| James Andrykowski | First Assistant Editor |
| Cassie Dixon | First Assistant Editor |
| Christos Voutsinas | First Assistant Editor |
| Lisa Fiorito | Researcher |
| Scheryl W Brown | Stunts |
| Stefanie Bruhn | Costume Supervisor |
| Wendy M. Craig | Costume Supervisor |
| Daniel Hargrave | Utility Stunts |
| Daniel Hargrave | Stunts |
| Sala Baker | Utility Stunts |
| Sala Baker | Stunts |
| Mickael Coedel | Animation |
| James Whitaker | Second Unit Director of Photography |
| Patrick Loungway | Second Unit Director of Photography |
| Trinh Tran | Associate Producer |
| Russell Bobbitt | Property Master |
| Andy Park | Concept Artist |
| Jackson Spidell | Stunt Double |
| Adam Cole | Post Production Coordinator |
| Bobby Jordan | Stunts |
| Joe Russo | Director |
| Anthony Russo | Director |
| Kerry Lyn McKissick | Script Supervisor |
| Chad Stahelski | Second Unit Director |
| David Leitch | Second Unit Director |
| Jerad Marantz | Concept Artist |
| Adrien Flanquart | VFX Artist |
| Maciej Kuciara | Conceptual Illustrator |
| Eckart Friz | Property Master |
| Loren Robinson | VFX Artist |
| Christoph Westphal | VFX Artist |
| Kenny Martinez | Thanks |
| Nancy Thurston | Utility Stunts |
| Heidi Moneymaker | Stunt Double |
| Daniel Bernhardt | Utility Stunts |
| Daniel Bernhardt | Stunts |
| Spiro Razatos | Second Unit Director |
| Spiro Razatos | Stunt Coordinator |
| Henry Kingi | Stunts |
| Andy Gill | Stunt Coordinator |
| Jack Gill | Stunt Driver |
| Jennifer White | Stunt Double |
| Joanna Bennett | Stunt Double |
| Keith Adams | Stunts |
| Donny Bailey | Stunt Driver |
| Chris Jai Alex | Stunts |
| Raven-Danielle Baker | Stunts |
| Shellita Boxie | Stunts |
| Jeanette Branch | Stunts |
| David E. Brown | Stunts |
| Shane Cardwell | Stunts |
| Fernando Chien | Utility Stunts |
| Vonzell Carter | Stunts |
| Kevin Cassidy | Stunts |
| Richard Cetrone | Stunts |
| Jwaundace Candece | Stunts |
| Doug Coleman | Stunt Coordinator |
| Jason Chu | Stunt Double |
| Alvin Chon | Stunt Double |
| Tye Claybrook Jr. | Stunts |
| Sarah Reagin | Stunts |
| Brandon Cornell | Utility Stunts |
| Stephen Conroy | Stunts |
| Wally Crowder | Utility Stunts |
| Lateef Crowder | Utility Stunts |
| Elizabeth Davidovich | Stunts |
| Phil Culotta | Utility Stunts |
| Gui DaSilva-Greene | Stunt Double |
| Keith Splinter Davis | Stunts |
| Julius Denem | Stunts |
| Kent De Mond | Stunts |
| Holland Diaz | Stunts |
| Thomas DeWier | Stunts |
| Josh Diogo | Stunts |
| Richard Epper | Utility Stunts |
| Guy Fernandez | Stunts |
| Gary Fry | Stunts |
| Alyma Dorsey | Stunts |
| Glenn Foster | Stunt Double |
| Kevin Dyer | Stunts |
| Austin Gill | Stunts |
| Garrett Hammond | Stunts |
| Sascha Girndt | Utility Stunts |
| Jas Hardy | Stunt Driver |
| Sam Hargrave | Fight Choreographer |
| Kandis Hargrave | Stunts |
| Regis Harrington | Stunt Driver |
| Jimmy Hart | Utility Stunts |
| Randy Haynie | Utility Stunts |
| Nicholas Hayner | Utility Stunts |
| Claudia Heinz | Utility Stunts |
| Adrian Hein | Stunt Double |
| Jason Charles Hill | Stunt Driver |
| Jermaine Holt | Utility Stunts |
| Damita Jane Howard | Stunts |
| Crystal Hooks | Stunt Double |
| C.C. Ice | Utility Stunts |
| Scott Hunter | Stunts |
| Courtney Julien | Utility Stunts |
| Precious Jenkins | Stunts |
| Antal Kalik | Stunts |
| Steve Kelso | Stunt Driver |
| Umar Khan | Stunts |
| Horace Knight Jr. | Stunts |
| Henry Kingi Jr. | Stunt Driver |
| Thomas J. Larsen | Stunt Double |
| Efka Kvaraciejus | Utility Stunts |
| Cheryl Lewis | Stunts |
| Bethany Levy | Stunts |
| Jalil Jay Lynch | Stunts |
| Tony Lazzara | Stunts |
| Jeremy Marinas | Utility Stunts |
| Maggie Macdonald | Stunts |
| Tony McFarr | Stunts |
| Hans Marrero | Stunts |
| Kyle Mclean | Stunt Double |
| Sarah Molasky | Stunt Double |
| Robert Nagle | Stunt Driver |
| Marque Ohmes | Utility Stunts |
| Phi-Long Nguyen | Stunts |
| Jane Oshita | Stunts |
| Eric Oram | Fight Choreographer |
| Allan Padelford | Stunt Driver |
| Travis Parker | Stunts |
| Denney Pierce | Stunts |
| Austin Priester | Stunts |
| Damion Poitier | Utility Stunts |
| Greg Rementer | Stunt Double |
| Brian A. Prince | Stunts |
| Jimmy N. Roberts | Stunt Double |
| Antjuan Rhames | Utility Stunts |
| Todd Schneider | Stunt Driver |
| Marvin Ross | Stunt Double |
| Maya Santandrea | Stunts |
| Nathaniel 'Nate' Scott | Stunt Driver |
| Cale Schultz | Stunts |
| Gregg Smrz | Stunt Driver |
| Brian Simpson | Utility Stunts |
| Buddy Sosthand | Utility Stunts |
| Larnell Stovall | Stunts |
| Daniel Stevens | Stunt Double |
| Eric Stratemeier | Stunts |
| Justin Sundquist | Stunt Double |
| Matt Thompson | Stunts |
| Todd Rogers Terry | Stunts |
| Aaron Toney | Fight Choreographer |
| Amy Lynn Tuttle | Stunts |
| Mark Aaron Wagner | Stunt Double |
| Eric VanArsdale | Stunts |
| Josh Wood | Stunt Double |
| Nico Woulard | Stunts |
| Joe Nin Williams | Utility Stunts |
| Kofi Yiadom | Stunt Double |
| Justin Yu | Stunts |
| James Young | Stunt Double |
| Kris Giacomazzi | Stunts |
| Gregory Fears | Stunt Driver |
| Emmanuel Manzanares | Stunts |
| Michael D. Jenkins | Stunt Driver |
| John J. Shim | Stunts |
| Christopher Kelly | Production Assistant |
| Riley Flanagan | Set Production Assistant |
| Monique Ganderton | Utility Stunts |
| Hiroshi Mori | Visual Effects |
| Darrin Prescott | Second Unit Director |
| Mickey Giacomazzi | Stunt Coordinator |
| Victor Rivas Alvarez | Visual Effects Production Assistant |
| Jeanie King | Executive Visual Effects Producer |
